GAS DETECTION GLOSSARY

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Aerosol is a suspension in air (or gas) of minute
particles of a liquid or a solid.
Alarm is an audible, visual, or physical presentation
designed to warn the instrument user that a specific level of a dangerous gas/vapor
concentration has been reached or exceeded.
Alarm Only Instrument is an instrument
providing an alarm(s) which does not have an integral meter or other readout device
indicating current concentration levels.
Alarm Set Point is the selected gas concentration
level where an alarm is activated.
Ambient Air is air to which the sensing element is
normally exposed.
Analyzer is an instrument which can determine
qualitatively and quantitatively the components in a mixture.
Approved is acceptance by the authority having
jurisdiction. In our literature, the term is considered synonymous with
"listed" and "certified."
Area Monitor is a term that is often misleadingly
applied to gas monitoring sensors that are installed in a regular grid pattern throughout
an area requiring monitoring. A true area monitor must be able to measure the
concentration of a substance at any point in three dimensional space in a defined value or
it must be able to indicate the total quantity of a substance that has penetrated a
defined volume.
Blocking
Certain conditions can cause a sensor not to function. when this happens, normal gas
sensing is blocked until the conditions are removed. The most common block is lack of
oxygen. Oxygen deprivation can be caused by sensor flooding and a clogged flame arrestor.
Calibration is the procedure
used to adjust the instrument for proper response (e.g., zero level, span, alarm and
range). Also see Remote Calibration
Calibration Gas is the known concentration(s) of
gas used to set the instrument span or alarm level(s).
Catalysis is a phenomena in which a relatively small
amount of material augments the rate of reaction without itself being consumed.
CATALYTIC BEAD SENSORS
Clean Air [Zero
Gas] is air that is free of any substance that will adversely affect the operation of
or cause a response of the instrument. Clean air is also called "zero air" or
"zero gas".
Coating
A form of sensor poisoning where a chemical reaction takes place which coats the surface
of a sensor, to the extent where it is unable to sense a gas. For instance exposure to a
small concentration of a volatile silicon compound can kill a catalytic sensor in less
than five minutes. Special poison resistant sensors are available from Net Safety.
Combustible Hydrocarbon (CHC)
is any organic gas or vapor which when mixed with air or oxygen is capable of the
propagation of flame away from the source of ignition when ignited.
Combustion is the rapid oxidation of a material
evolving heat and generally light.
Consumables are those materials or components which
are depleted or require periodic replacement through normal use of the instrument.
Control Unit/Module [Controller] is
that portion of a multi-part gas detection instrument which is not directly responsive to
the gas but which responds to the electrical signal obtained from one or more detector
heads to produce an indication, alarm, or other output function. The control unit contains
the operating controls such as zero, span and alarm setpoint adjustments along with
readouts, status indicators, recorder outputs and relay contacts.
CSA An approval agency based in Canada.
Canadian Standards Association
Detector Head is the gas-responsive portion of a gas
detection instrument located in the area where sensing the presence of gas is desired. Its
location may be integral with or remote from any circuitry.
Diffusion is a process by which the atmosphere being
monitored is transported to the gas-sensing element by natural random molecular movement.
This movement is accelerated by thermal energy.
Electrical Noise -
Electrical noise has been creating problems ever since
the first antennas were installed and lightning storms interfered. Almost every
form of electrical or electronic device has had to live with the problem at one
time or another. Today, we recognize that almost any device which operates on
the principle of moving an electron from one point to another can be a receiver
of electrical noise. Since the problem first became obvious to early radio
engineers, the term 'radio frequency interference' (RFI)
was most often applied. As engineers spread the use of electronics beyond its
beginnings in radio communication, it was found that electrical interference
didn't confine itself to the radio spectrum. The newer term 'electromagnetic
interference (EMI) acknowledges the fact that electrical interference
encompasses the entire electromagnetic spectrum from the lowest magnetic
frequencies through the highest microwave frequencies.
ELECTROCHEMICAL SENSORS
Etching Volatilization is a form of sensor poisoning which removes the sensor catalyst. Special
poison resistant Catalytic Bead sensors are available from Net Safety.
Explosion is an uncontrolled chemical reaction which
generates a large amount of heat and gas in a short period of time.
Fail Safe. Any system that cannot fail in any mode
without providing a directly observable indication of failure. Consider an electrical
relay with a set of contacts that are open when it is un-powered. If a power source and a
light bulb are connected in series with the contacts, the lamp will glow when the relay is
energized. If the goal of this system is to insure that the relay has power, then this
system is said to be fail safe. If the lamp, relay contacts, lamp power source relay coil,
or the relay coil power supply fail, then the lamp extinguishes itself providing a
directly observable foolproof indication of failure.
Fixed Installation. The terminology commonly
used to indicate that a gas monitor is permanently installed, such as in the control panel
of a control room. Occasionally gas monitors are mounted in vehicles, such as fire trucks
or tankers. These are also generally referred to as fixed installation monitors.
Flame Arrestor
Its purpose is to prevent flame propagation from the heated sensor side of the sensor. It
reduces the differential cooling effect of wind on the sensing element and protects the
sensor from flooding by a high velocity of gas. It also protects
the sensing element from damage during handling. It should be checked for proper
attachment and fit, and for signs of corrosion, dirt or moisture. An area must be
declassified (free from Combustible Gas) before a flame arrestor can be removed from a
catalytic system.
Flame proof or Explosion Proof
Flame paths through housing flanges or flame arrestors are dimensioned such that the hot,
gaseous products of internal explosion, which may leak out of the enclosure, will be
sufficiently cooled to prevent igniting the specific flammable surroundings. The
enclosures are strong enough to withstand the internal explosions without damaging these
controlled flame paths. Surfaces that may contact the flammable atmospheres have maximum
temperatures below the ignition point of the specific gas or vapor to be encountered.
Flammable (Explosive) Limits. For
gases or vapors which form flammable mixtures with air or oxygen, there is a minimum
concentration of vapor in air or oxygen below which propagation of flame does not occur on
contact with a source of ignition. There is also a maximum proportion of vapor or gas in
air above which propagation of flame does not occur. These boundary-line mixtures of vapor
or gas with air, which if ignited will just propagate flame, are known as the "lower
and upper flammable limits" (LFL and UFL) or the "lower and upper explosive
limits" (LEL and UEL), and are usually expressed in terms of percentage by volume of
gas or vapor in air. LEL and LFL are different terms for the same concept and can be used
interchangeably. In popular terms, a mixture below the lower flammable limit is too
"lean" to burn or explode and a mixture above the upper flammable limit too
"rich" to burn or explode.
Flammable (Explosive) Range. The range of flammable
vapor or gas-air mixture between the upper and lower flammable limits is known as the
"flammable range", also often referred to as the "explosive range".
For example, the lower limit of flammability of acrylonitrite at ordinary ambient
temperatures is approximately 3 percent vapor in air by volume, while the upper limit of
flammability is about 17 percent. All concentrations by volume of acrylonitrite vapor in
air falling between 3 percent and 17 percent are in the flammable or explosive range.
Flashpoint is the minimum temperature at which a liquid
gives off a sufficient vapor to reach 100% LEL (sufficient vapor to form an ignitable
mixture with the air near the surface of the liquid).
Flooding
Sensor flooding occurs when a gas concentration at the sensor exceeds its stoichiometric
mixture. The signal from the sensor reverts to zero because the mixture in the air is too
gas-rich to burn.
FM Certification - Industrial and commercial companies around the
world rely on products and services that are FM Approved and specification tested to
protect their properties from loss. The FM APPROVED mark, which is backed by scientific
research and testing, tells customers your product conforms to the highest standards.
Factory Mutual Research Corporation
Gas is a phase of matter which expands indefinitely to fill a
containment vessel. Characterized by a low density.
Gas Detection Instrument is an assembly
of electrical, mechanical and chemical components (either a single integrated unit or a
system comprised of two or more physically separate but interconnected component parts)
which senses and responds to the presence of gas in air mixtures.
Gas Sensing Element (Sensor) is the
particular subassembly or element in the gas detection instrument which, in the presence
of a gas, produces a change in its electrical, chemical, or physical characteristics.
Hydrogen Sulfide
is interchangeable for: hydrogen sulphide, H2S, dihydrogen sulfide, and hydrogen
sulfide gas.
IDLH (Immediately Dangerous to Life and Health) represents
the maximum concentration level of a substance from which one could escape within 30
minutes without escape-impairing symptoms or any irreversible effects (For instance 300
ppm for Hydrogen Sulfide).
Ignitable Mixture A mixture within the flammable
range (between the lower and upper flammable/explosive limits) that, when ignited, is
capable of the propagation of flame away from the source of ignition.
Ignition Temperature is the minimum
temperature necessary to initiate combustion (oxidation) and have self-sustained
combustion of the solid, liquid, gas, or vapor of interest.
INFRARED GAS DETECTORS
Interference
An interferent is any gas other than the target gas that will cause a gas detecting sensor
to give a signal. In the case of a combustible sensor, any combustible gas or vapor will
cause a signal.
Intrinsic Safety Electrical apparatus and its
associated wiring in the hazardous location is intrinsically safe when it is designed to
operate with insufficient electrical or thermal energy, under either normal or abnormal
conditions, to ignite the specific hazardous atmospheric mixture.
ISA -
The International Society of Automation
Liquid is a phase of matter which is free to conform to a
shape of a vessel but has a fixed volume and has a greater density than a gas.
Lower Explosive Limit (LEL) |
Lower Flammable Limit (LFL) -
The lower explosive limit (LEL) or lower flammable limit (LFL) of a combustible gas is
defined as the smallest amount of the gas that will support a self-propagating flame when
mixed with air (or oxygen) and ignited. In gas-detection systems, the amount of gas
present is specified in terms of % LEL: 0% LEL being a combustible gas-free atmosphere and
100% LEL being an atmosphere in which the gas is at its lower flammable limit. The
relationship between % LEL and % by volume differs from gas to gas. For data on other
gases, refer to the most recent edition of the Handbook of Chemistry and Physics
published by the C.R.C. Press. Typical settings for the alarm circuit are 20% for the low
alarm, 40% for the high alarm and 60% for the high-high alarm.
The LEL of a gas is affected by the temperature and pressure: as the temperature
increases, the LEL decreases and hence the explosion hazard increases; the relationship
between LEL and pressure is fairly complex, but at approximately one atmosphere a pressure
increase usually lowers the LEL. The LEL of a gas is not significantly affected by the
humidity fluctuations normally encountered in the operation of a gas-detecting system.
Monitor is an instrument used for continuous measurement
of a condition which must be kept within prescribed limits.
Monitors are not the same as analyzers. An analyzer is capable of determining the quality,
quantity and/or type of specific substance or substances in a mixture. A monitor
continuously measures a condition which must be kept within prescribed limits.
NEMA
National Electrical Manufacturers Association. Technical standards for
electrical equipment - specifically to Net Safety, explosion-proof enclosures.
Nonsparking Nonsparking circuits are those which
contain no contacts or in which contacts are isolated from the surrounding atmosphere such
as by hermetic sealing.
Nominal Voltage is the voltage given by the
manufacturer as the recommended operating voltage of their gas detection equipment. If a
range (versus a specific voltage) is given, the nominal voltage shall be considered as the
midpoint of the range, unless otherwise specified.
Nonincendive
Nonincendive circuits are those which may spark under normal operating conditions, but
which may not release enough energy to cause ignition. Circuits may contain enough energy
for potential ignition should both the equipment fail and the process fail (two concurrent
failures).
Oxidation-Reduction
In its most basic form Oxidation is a chemical reaction with oxygen. Example: the
oxidation of Methane (formula). In this example, molecular Oxygen is the oxidizing agent
and the substance reacting with oxygen (methane) is called the reducing agent. Confusingly
the reducing agent (Methane) can also be called an oxidizable gas. Compounds containing
oxygen can yield oxygen in a reaction and are also called oxidizing agents. Oxidation is a
reciprocal process in which one agent is reduced and one oxidized. A more complete way of
describing oxidation is through the transfer of electrons. The substance oxidized loses
electrons. The substance reduced gains electrons. Under suitable conditions, the
oxidation-reduction reaction produces a flow of current.
See electrochemical sensor
Point Monitor All popular gas monitors are point
monitors. This means that their sensors are only capable of indicating the concentration
of a substance at a single point in three dimensional space.
Selection of the proper point in three dimensional space at which to place a sensor or sample probe
is the most important element in design a gas monitoring system.
Poisons Sensors can be quickly destroyed (or poisoned) by
certain materials. Even low concentrations of poisoning substances can cause serious
problems. The two most common phenomena are coating and etching. [ Our Propritary SensorGuard
technology prevents oversaturation (100%LEL) through our advanced micro-processor automatically
terminating the current to the sensor when the presence of concentrated gas remains in the area.
This prevents premature sensor burn-out and dramatically increases the sensor's lifespan.]
Portable refers
to a self-contained, battery-operated or transportable gas monitor worn or carried by the
person using it. A gas detector that can be carried.
Ported Sensor provides
a 1/4" NPT connection on the side of a sensor body or sensor adaptor for
delivery of calibration gas. Typically used when sensor is located in a
hard-to-reach or hazardous location.
PPM - Parts Per Million
Range is the series of outputs corresponding to values of
concentrations of the gas of interest over which accuracy is ensured by calibration.
Remote Calibration
Conventional gas detectors require two people with walkie talkies, one at the controller
to adjust zero and span and one at the sensor to apply calibration gas. With Net Safety's
one-person calibration, zero and span adjustments are made at the sensor by the same
person applying calibration gas. Also see Calibration
Sample Draw refers to a method to cause deliberate
flow of the atmosphere being monitored to a gas-sensing element.
SEMICONDUCTOR SENSORS (Solid State MOS)
Sensing Element
A sensing element is unique to each gas to be monitored. The element is constructed to
plug into a circuit board in the sensor housing. All Net Safety sensor elements can
easily be replaced in the field.
Sensor
A gas detecting sensor converts the presence of a gas or vapor into an electrically
measurable signal. The sensor is the heart of a gas monitor. The system is as good as the
sensor.
Solid is a phase of matter characterized by a definite
volume and definite shape. A solid resists external forces to change shape.
Span is the algebraic difference between the upper and lower
values of a range.
Stationary refers to a gas detection instrument
intended for permanent installation in a fixed location.
Stoichiometric. The exact percentage of two or more
substances which will react completely with each other leaving no unreacted residue. For
example, a 7% mixture of methane by volume in air will react completely with the oxygen
present leaving only CO2 and H2O as residue. If the methane
concentration here is less than 7%, there would be oxygen left over. If the methane
concentration were greater than 7%, there would be methane left over.
Test Gas is a known concentration of the gas to be
detected diluted with clean air.
Threshold Limit Value Time-Weighted Average
(TLV-TWA) is the time-weighted average concentration of a substance for a normal
8-hour work day and a 40-hour work week, to which nearly all workers may be repeatedly
exposed, day after day. (OSHA)
Toxic Gas or Vapor. Any substance which causes illness
or death when inhaled or absorbed by the body in relatively small quantities. H2S
is a highly toxic gas.
Transmitter
A transmitter in a gas detection system amplifies the signal from the sensor and converts
it into a more convenient form for transmission. Some monitors collect sensor signals
without the use of transmitters.
Trouble Signal is a signal (contact, transfer,
and/or visible or audible signal) advising an instrument user of conditions such as input
power failure, an open circuit breaker, a blown fuse, loss of continuity to the detector
head, defective gas-sensing element, or significant downscale indication
Universal Sensor
This sensor allows the user to switch sensor elements and flame arrestors instead of the
whole sensor. A sensor is thereby replaced with a minimum of cost in time and money.
Vapor is the gaseous state of a material below its boiling
point.
Vapor Density relates the molecular
weight of a gas to the molecular weight of air. Vapor density is the weight
of a volume of pure vapor or gas (with no air present)
compared to an equal volume of dry air, at the same temperature and pressure. This
information assists in determining the location of a sensor. A vapor density figure of
less than 1 indicates that the vapor is lighter than air and will tend to rise in a
relatively calm atmosphere. A figure greater than 1 indicates that the vapor is heavier
than air and may travel at low levels for a considerable distance to a source of ignition
and flash back (if the vapor is in the flammable range). Note that some gases such as
ethane have a vapor density of 1 and may be present at low levels or may rise
significantly, dependent upon ambient conditions.
Zero Gas
Zero gas is clean air, and is an excellent way of insuring that a small release of gas is
not near the sensor while zeroing the sensor signal during calibration.
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